The NLS_INSTANCE_PARAMETERS view reflects parameters set for your instance in the init.ora file or the server parameter file (spfile).
Source: James Koopman in Databasejournal.com
This matches my settings for a random database:
SQL> show parameter nls_ NAME TYPE VALUE ------------------------------------ ----------- ------------------------------ nls_comp string BINARY nls_language string AMERICAN nls_length_semantics string BYTE nls_nchar_conv_excp string FALSE nls_territory string AMERICA SQL> SELECT * FROM NLS_INSTANCE_PARAMETERS WHERE value IS NOT NULL; PARAMETER VALUE ------------------------------ ---------------------------------------- NLS_LANGUAGE AMERICAN NLS_TERRITORY AMERICA NLS_COMP BINARY NLS_LENGTH_SEMANTICS BYTE NLS_NCHAR_CONV_EXCP FALSE 5 rows selected.